Conformations of the Esters. IV. The Conformations of Carbamates
- 1 November 1971
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 44 (11) , 3148-3151
- https://doi.org/10.1246/bcsj.44.3148
Abstract
It has been confirmed from an infrared spectral study of the C=O, N–H, and N–D stretching regions that primary, secondary, and tertiary carbamates take the s-cis and s-trans conformations with respect to the ester group. The nuclear magnetic resonance spectra and the results of dipole-moment studies support this conclusion.This publication has 11 references indexed in Scilit:
- Conformations of the Ester GroupBulletin of the Chemical Society of Japan, 1970
- Hindered rotation in N,N-dimethylcarbamatesThe Journal of Organic Chemistry, 1967
- cis and trans Configurations of the Peptide Bond in N-Monosubstituted Amides by Nuclear Magnetic ResonanceJournal of the American Chemical Society, 1964
- The structural configuration of some α-substituted secondary acetamides in dilute ccl4 solutionSpectrochimica Acta, 1963
- The infrared spectra of some simple N-substituted amides in the vapor stateJournal of Molecular Spectroscopy, 1963
- Infrared Spectra and Normal Vibrations of N-Methylformamides HCONHCH3, HCONDCH3, DCONHCH3 and DCONDCH3Bulletin of the Chemical Society of Japan, 1962
- Studies on l-Alkenyl Isocyanates and Their Derivatives1The Journal of Organic Chemistry, 1961
- The Carbonyl Absorption of Carbamates and 2-Oxazolidones in the Infrared RegionJournal of the American Chemical Society, 1957
- Vibrational spectra and geometrical isomerism in amidesSpectrochimica Acta, 1956
- The Molecular Structure of N-MethylacetamideJournal of the American Chemical Society, 1950