Reactions of relevance to the chemistry of aminoglycoside antibiotics. Part 13. A novel synthesis of benzyl ethers
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 10,p. 2184-2190
- https://doi.org/10.1039/p19800002184
Abstract
Benzyl ethers were prepared from alcohols by reaction with chloro(phenylmethylene)dimethylammonium chloride and sodium hydrogen telluride in sequence. The salt (1)[Me2NC(R1)OR2Cl–; R1= H, R2= cholest-5-en-3β-yl] and sodium borohydride gave the borane complex of 3β-dimethylaminomethoxycholest-5-ene. Salt (1; R1= Ph, R2= cholest-5-en-3β-yl or 5α-cholestan-3β-yl) and ammonia or hydrazine gave the steroidal benzimidates or benzhydrazonate.This publication has 2 references indexed in Scilit:
- Reactions of relevance to the chemistry of aminoglycoside antibiotics. Part 6. A simple preparation of chlorohydrin benzoates from 1,2-and 1,3-glycolsJournal of the Chemical Society, Perkin Transactions 1, 1977
- Reactions of relevance to the chemistry of aminoglycoside antibiotics. Part 8. Synthesis and properties of O-alkyl selenoestersJournal of the Chemical Society, Perkin Transactions 1, 1977