The Structurally Regular trans-1,4-Poly(chloroprene)
- 1 December 1970
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 4 (8) , 1679-1703
- https://doi.org/10.1080/00222337008059515
Abstract
Radiation polymerization of large crystals of chloroprene formed within the temperature range -130 to -180°C has yielded the stereoregular trans-1,4-poly(2-chloro-1,3-butadiene). The monomer was found to have a glass transition temperature of ca. -180°C. Polymerization of monomer rapidly cooled to below -180°C was difficult and gave only structurally irregular polymer in low yield.Keywords
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