Oligomers of allene. Part II. Dimers and trimers formed in the thermal polymerisation of liquid allene
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society C: Organic
- p. 368-372
- https://doi.org/10.1039/j39670000368
Abstract
Thermal polymerisation of liquid allene affords two dimers, 1,2-dimethylenecyclobutane and 1,3-dimethylene-cyclobutane, as well as three trimers, 1,5(and/or 1,6)-dimethylenespiro[3,3]heptane, 1,2,4-trimethylenecyclohexane and 3-methylenebicyclo[4,2,0]octa-1(6)-ene. A radical mechanism is proposed.Keywords
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