Synthesis and molecular structure of the first organometallic nitride cubane: [{Ti(η5-C5Me5)}4(µ3-N)4]
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 2185-2186
- https://doi.org/10.1039/c39950002185
Abstract
The ammonolysis of [Ti(η5-C5Me5)(NMe2)3] at 90 °C affords the nitride complex [{Ti(η5-C5Me5)}4(µ3-N)4]; the X-ray crystal structure analysis shows a Ti4N4 core clearly similar to the structural motif of cubic titanium nitride.Keywords
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