Some Parameters Affecting the Flotation of Cationic Surfactants
- 1 February 1972
- journal article
- research article
- Published by Taylor & Francis in Separation Science
- Vol. 7 (1) , 25-41
- https://doi.org/10.1080/00372367208058969
Abstract
A study was made of the flotation of very dilute solutions of two cationic collectors, hexadecyltrimethylammonium chloride (HTMAC) and dodecyl-pyridinium chloride (DPC), in the presence of added electrolytes. The concentration, charge, and nature of these electrolytes were found to have a pronounced effect on the rates of flotation. The determinations were made at two different gas flow-rates; unexpectedly, the ratios of the flotation rates were found to be different to the total surface areas of the bubbles passing. The discrepancy can be explained on the basis of the repulsions which exist between bubbles due to the charged surfactant species which are adsorbed on them. Small bubbles, which lack kinetic energy, are unable to penetrate the lower reaches of the foam and are swept back into the solution. The latter, therefore, contains too high a proportion of small bubbles which leads to an erroneous estimate of the total surface area available, and casts doubt on the validity of a photographic method which has been used in the past. The flotation of DPC proved considerably more difficult than that of HTMAC due to the reduced chain-length and lower surface activity of the former.Keywords
This publication has 6 references indexed in Scilit:
- Studies in the Mechanism of Sublate Removal by Solvent Sublation. Part IISeparation Science, 1970
- Comparison of Variables in Ion and Precipitate FlotationIndustrial & Engineering Chemistry Process Design and Development, 1966
- The effect of temperature upon foam fractionationJournal of Oil & Fat Industries, 1965
- Foam Fractionation of Cationic Surfactants: Effect of Inorganic Acids and BasesNature, 1964
- Continuous foam fractionation: The effect of operating variables on separationAIChE Journal, 1964
- Effect of the Foam-Liquid Solution Interface On Continuous Foam SeparationNature, 1963