Studies on tertiary phosphine–hydride and –hydridoborohydride compounds of nickel and palladium
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 469-474
- https://doi.org/10.1039/j19710000469
Abstract
The isolation and properties of the complexes trans-(R1 3P)2M1H(BH4) and trans-(R1 3P)2M2HM, where M1= Ni or Pd; R1= Pri, cyclohexyl, M2= Pd, X = Cl, Br, I, or NCS, are described. Exchange reactions of the type (i) where R2= Et, Prn, and Bun, have been studied by 1H n.m.r. (R2 3P)2M1XH [graphic omitted] (R1 3P)(R2 3P)M1HX [graphic omitted] (R2 3P)2M1HX (i)Keywords
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