Abstract
Incorporation of sterically encumbered aryl ligands permits the isolation and characterization of stable sodium and potassium tellurolates; X-ray structures of the monomers [Na(tmed)2][Te(2,4,6-Me3C6H2)] and [K(18-C-6)][Te(2,4,6-Pri 3C6H2)] are described (tmed N,N,N′,N′-tetramethylethylenediamine; 18-C-6 1,4,7,10,13,16-hexaoxacyclooctadecane).

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