A mixed-linker porphyrin framework with CdI2-type topology
- 9 April 2008
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in CrystEngComm
- Vol. 10 (7) , 824-826
- https://doi.org/10.1039/b720035h
Abstract
A novel metal–organic framework, [(Co(cis-ZnDCPP)(bpy)]·4DMF·H2O (cis-ZnDCPP = zinc 5,10-di(4-carboxyphenyl)-15,20-diphenylporphyrin; bpy = 4,4′-bipyridine; DMF = dimethyl formamide), has been synthesized from the solvothermal reaction and exhibits unique CdI2 layers constructed from paddle-wheel buiding units, Co2(COO)4, cis-ZnDCPP, and 4,4′-bipyridine linker.Keywords
This publication has 23 references indexed in Scilit:
- Coordination Polymers that Contain Accessible Metal Centres ‐ Synthesis and Structure of a Nickel Cluster Connected Porphyrin NetworkZeitschrift für anorganische und allgemeine Chemie, 2005
- Microporous Porphyrin SolidsAccounts of Chemical Research, 2005
- Coordination Polymers of Tetra(4-carboxyphenyl)porphyrins Sustained by Tetrahedral Zinc Ion LinkersCrystal Growth & Design, 2004
- Porphyrin Clathrates. Crystal Structures of Two Unexpected Products Obtained by Solvothermal Reactions of Pt-tetra(4-carboxyphenyl)porphyrin with Copper AcetateJournal of inclusion phenomena and molecular recognition in chemistry, 2004
- A Robust Microporous Zinc Porphyrin Framework SolidInorganic Chemistry, 2003
- A functional zeolite analogue assembled from metalloporphyrinsNature Materials, 2002
- A calcium-bridged porphyrin coordination networkJournal of Porphyrins and Phthalocyanines, 2002
- Porphyrin sieves. Designing open networks of tetra(carboxyphenyl)porphyrins by extended coordination through sodium ion auxiliariesNew Journal of Chemistry, 2001
- Frameworks for Extended Solids: Geometrical Design PrinciplesJournal of Solid State Chemistry, 2000
- Coordination Networks ofC3vandC2vPhenylacetylene Nitriles and Silver(I) Salts: Interplay of Ligand Symmetry and Molecular Dipole Moments in the Solid StateChemistry of Materials, 1999