Fluxional dirhodium complexes: crystal and molecular structure of [Rh2(CO)2(µ-SPh)2(C8H8)]
- 1 January 1977
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 434-436
- https://doi.org/10.1039/c39770000434
Abstract
Variable temperature n.m.r. studies of complexes [Rh2(CO)2(µ-SPh)2L] and [Rh2(µ-SR)2L2](R = Me, Et, Pri, But, or Ph; L = cyclo-octatetraene or cyclo-octa-1,5-diene) reveal the existence of both an olefin rotation and an inversion of non-planar Rh2S2 ring; this non-planarity is established by an X-ray diffraction study of [Rh2(CO)2(µ-SPh)2(C8H8)].Keywords
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