On the l z-conserving energy sudden approximation for atom–diatom scattering
- 15 May 1978
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 68 (10) , 4631-4640
- https://doi.org/10.1063/1.435570
Abstract
The utility of a lz‐conserving approximation, resulting from only energy sudden approximation to the exact space fixed coupled equations, is investigated for atom–diatom scattering. It is shown that the expressions for various transitions probabilities and differential cross sections may be obtained after evaluating relatively small number of lz‐conserving S‐matrix elements. Numerical comparisons with IOS and CC results are given for Ar–N2 and Ar–Tlf for a set of previously well studied parameters.Keywords
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