New Daucane Esters from Ferula tingitana

Abstract
In addition to the three known daucane esters (2,3,8) and one phenylpropanoid (9), the petroleum ether extracts of the roots of Ferula tingitana yielded four new daucane esters: 14-p-anisoyloxy-dauc-4,8-diene (1), acetyltingitanol (4), acetyldesoxodehydrolaserpitine (5), and 4-.beta.-hydroxy-6-.alpha.-p-hydroxybenzoyloxy-10-.alpha.-angeloyloxydauc-8-ene (6). A possible biogenetic pathway for 1,5-cis- and 1,5-trans-daucanes is presented.

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