Synthesis and properties of fac-Re(dmbpy)(CO)3CHO (dmbpy = 4,4′-dimethyl-2,2′-bipyridine), a possible intermediate in reductions of CO2 catalyzed by fac-Re(dmbpy)(CO)3Cl
- 1 October 2001
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 20,p. 2082-2083
- https://doi.org/10.1039/b106270k
Abstract
Synthesis of fac-Re(dmbpy)(CO)3CHO 2 and its reactions with CO2 in DMF and DMSO have been conducted; 2 transfers hydride to CO2 to give Re(dmbpy)(CO)4 + OCHO− 5 which is rapidly transformed to fac-Re(dmbpy)(CO)3- (OCHO) 3 in DMF, thus supporting the viability of 2 in photocatalytic reactions of fac-Re(dmbpy)(CO)3Cl with CO2.Keywords
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