Abstract
The correlation of the 0-0-transitions and the maxima of absorption and fluorescence with the σ-Hammett constants. The correlation of the 0-0-transitions and the maxima of absorption and fluorescence with the ff-Hammett constants lead to conclusions concerning the changes in the gap of the state involved and their curvatures due to substitution. The formalism can be applied also using other LFER parameters than σ-Hammett constants.

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