Synthesis, structures and reactions of new thermally stable silylenes
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1931-1932
- https://doi.org/10.1039/c39950001931
Abstract
Two representatives 1a and 1b of a new series of stable but reactive bis(amino)silylenes, derived from the N,N′-dineopentyl-1,2-phenylenediamido ligand RC6H3[(CH2But)]2, have been prepared by reductive elimination from RC6H3[[graphic omitted]SiCl2 and characterised by NMR spectroscopy and for 1a X-ray crystallography; the silyienes [graphic omitted](CH2But)]2C6H3-1,2-R (R = H 1a or 4-Me 1b) readily undergo oxidative addition with EtOH or Mel.Keywords
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