Rhodium(I)-catalysed dismutation of electron-rich olefins: rhodium(I) carbene complexes as intermediates
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 927-928
- https://doi.org/10.1039/c39720000927
Abstract
Dismutation of two different electron-rich olefins C2X4 and C2Y4 proceeds only in the presence of an additive, compounds such as L(Ph3P)2RhCl (L = Ph3P or CO) being particularly effective; carbene complexes L(Ph3P)Rh(CX2)Cl and L(Ph3P)Rh(CY2)Cl are isolable intermediates and the active catalysts.Keywords
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