Cyclic boron compounds. Ring strain in the B-phenyl and B-butyl dioxaboron heterocycles
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 3339-3345
- https://doi.org/10.1039/j19700003339
Abstract
The solution thermochemistry at 25 °C of [graphic omitted], RB(OEt)2, [graphic omitted] [R = Ph or Bun, n= 2, 3, or 4] is described. Appropriate enthalpies of transition are determined and cyclic strain energies of the heterocycles are estimated. The influence of steric and electronic effects on these strain energies is discussed.Keywords
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