Abnormal reaction of an aryl azide confined in a calix[6]arene skeleton
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1899-1900
- https://doi.org/10.1039/c39950001899
Abstract
Photolysis of an aryl azide embedded in a m-phenylene-bridged p-tert-butylcalix[6]arene 2 results in the formation of unusual reaction products 3 and 4via the transannular addition reaction of an initially formed nitrene intermediate; the molecular structure of 4 was determined by X-ray crystallographic analysis.Keywords
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