Calculation of the electron binding energies of atomic Zn, Cd and Hg: evidence of a many-electron shift in the gas phase X-ray photoemission spectra of core levels
- 28 May 1980
- journal article
- Published by IOP Publishing in Journal of Physics B: Atomic and Molecular Physics
- Vol. 13 (10) , 1953-1960
- https://doi.org/10.1088/0022-3700/13/10/005
Abstract
Relaxed orbital binding energies have been calculated using the relativistic Hartree-Fock method for Zn, Cd and Hg. The results are in excellent agreement with relaxed orbital relativistic Hartree-Fock-Slater calculations. A residual discrepancy is found between these theoretical results and experimental values of the binding energies which, for the N shell of Hg, can be correlated with the lifetime of the core hole.Keywords
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