X-Ray crystal structure of a planar, high-spin iron(II) complex of a pentadentate unsaturated macrocycle formed by reaction of 2,9-di(1-methylhydrazino)1,10-phenanthroline monohydrochloride with 2,6-diacetylpyridine
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 828-829
- https://doi.org/10.1039/c39780000828
Abstract
The crystal structure of a high spin iron(II) complex with a pentadentate nitrogen macrocycle, that bears certain structural similarities to porphyrins, demonstrates that the metal ion sits in the ligand plane, a stereochemistry that is attributed to the slightly larger hole size relative to porphyrins.This publication has 1 reference indexed in Scilit:
- Stereochemistry of manganese porphyrins. 3. Molecular stereochemistry of .alpha.,.beta.,.gamma.,.delta.-tetraphenylporphinato(1-methylimidazole)manganese(II)Journal of the American Chemical Society, 1977