Real-time probe of reaction centers in solid combustions on the subsecond time scale

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Abstract
A quick-scanning extended x-ray-absorption fine-structure (QEXAFS) technique has been devised to follow the local atomic coordination changes about selected reactants in a class of highly exothermic solid-combustion reactions. Real-time EXAFS measurements during the combustion were made in the time frame of a few seconds. By tuning the monochromator to a specific energy, at which maximum changes occur in an EXAFS feature of an element transforming from the reactant to the product phase, a time resolution of 20 ms was achieved. The Ni+Al→NiAl reaction has been investigated in some detail in light of a possible intermediate phase in the so-called ‘‘after-burn’’ region. The present QEXAFS findings together with the recent time-resolved diffraction data on the same system lends experimental insights into the structural macrokinetics of this class of combustion systems.