A Novel Stereoselective Route to Alkyl 2-Deoxy-?-D-glucosides via S-(2-Deoxy-?-glucosyl) Phosphorodithioates
- 1 January 1983
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 2 (1) , 99-103
- https://doi.org/10.1080/07328308308058811
Abstract
Intense interest in sugar components of anthracycline antibiotics and antitumor drugs generated a need for stereoselective methods of synthesis of 2-deoxy sugar glycosides. Although several efficient procedures leading to 2-deoxy-α-glycosides were elaborated, there is no satisfactory general procedure leading to the β-anomers. The methods described are not stereoselective and involve separation of anomeric intermediates of glycosides.Keywords
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