Chemical Reaction of Electron Donor-Acceptor System: Reaction Mechanism of the Tricyanovinylation Reaction of N,N-Dimethylaniline with Tetracyanoethylene
- 1 July 1979
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 52 (7) , 2110-2113
- https://doi.org/10.1246/bcsj.52.2110
Abstract
The decay of the charge-transfer (CT) absorption band in the tricyanovinylation reaction of N,N-dimethylaniline (DMA) with tetracyanoethylene (TCNE) in 1,2-dichloroethane was followed by the electronic absorption measurement. Primary hydrogen isotope effect was observed for the decay of the CT-band in line with the mechanism:Keywords
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