Selective Methylation of Phenol, Aniline and Catechol with Dimethyl Carbonate Over Calcined Mg-Al Hydrotalcites

Abstract
Calcined Mg-Al hydrotalcites (Mg/Al=3) can be used as an efficient catalyst in the selective O-methylation of phenol and catechol and N-monomethylation of aniline employing dimethylcarbonate (DMC) as a methylating agent in vapor phase at 275°C.

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