METAL OXIDE ALKOXIDE POLYMERS: PART IV. THE HYDROLYSIS OF SOME TANTALUM ALKOXIDES
- 1 January 1962
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 40 (1) , 62-72
- https://doi.org/10.1139/v62-011
Abstract
Ebulliometric studies on the hydrolysis of tantalum pentaalkoxides Ta(OR)5, where R = Me, Prn, Bun, and Bus, have furnished important data on the polymeric nature of tantalum oxide alkoxides. It is shown from the variation of number-average degrees of polymerization as a function of degree of hydrolysis that the polymers conform to certain structural models. The structural models involve 6-co-ordinated tantalum.Keywords
This publication has 2 references indexed in Scilit:
- METAL OXIDE ALKOXIDE POLYMERS: PART II. THE HYDROLYSIS OF TANTALUM PENTAETHOXIDECanadian Journal of Chemistry, 1961
- METAL OXIDE ALKOXIDE POLYMERS: PART I. THE HYDROLYSIS OF SOME PRIMARY ALKOXIDES OF ZIRCONIUMCanadian Journal of Chemistry, 1961