Diphosphine platinum(II) photo-oxidants. Synthesis and photochemistry of luminescent diphosphine platinum(II) complexes of 5,6-dimethyl-1,10-phenanthroline
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 140-142
- https://doi.org/10.1039/c39900000140
Abstract
The [Pt(P–P)(5,6-Me2phen)]2+ complexes (P–P = chelating diphosphine, 5,6-Me2phen = 5,6-dimethyl-1,10-phenanthroline) exhibit photoluminescence at 490–495 nm: the excited state lifetimes and excited oxidation potentials are 22–25 µs and ∼2.1 V vs. normal hydrogen electrode (NHE), respectively.Keywords
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