Evaluation of the thermodynamic parameters for the interconversion of the conformational isomers of two N-acyl-prolines by nuclear magnetic resonance spectroscopy
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 19,p. 1209-1210
- https://doi.org/10.1039/c29710001209
Abstract
Study of the 1H n.m.r. spectra of the N-acyl-prolines (I) and (II) in deuteriochloroform over a range of temperature has enabled the thermodynamic parameters for the interconversion of such conformers by rotation about the N–CO bond to be evaluated for the first time.Keywords
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