Halocarbon complexes of platinum(II)
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 317-319
- https://doi.org/10.1039/c39910000317
Abstract
Chelate-stabilised halocarbon–platinum(II) complexes of the general type cis- and trans-[MePt(η2-Ph2PY)(η1-Ph2PY)][BF4] where Y = CH2CH2Cl, o-C6H4Cl or o-CH2C6H4X, X = Cl, Br or l, are reported and the relative trans-influence of the halocarbon donors is discussed; the X-ray crystal structures of [MePt(η2-Ph2PCH2CH2Cl)(η1-Ph2PCH2CH2Cl)][BF4] and [MePt{η2-Ph2P(o-C6H4Cl)}{η1-Ph2P(o-C6H4Cl)}][BF4] have been determined.Keywords
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