Specific-Heat Critical Exponents near the Nematic—Smectic-APhase Transition

Abstract
We have applied a recently developed method for sensitive calorimetric measurements to investigate the nematic—smectic-A phase transition in pure N-p-cyanobenzylidene-pn-octyloxyaniline. The results indicate a very weak first-order transition with a transition entropy of (0.017±0.002)R0. The critical exponents of the specific-heat anomaly have nonclassical values α=0.16±0.01 and α=0.14±0.02.