Magnetic exchange in a copper(II) dimer with oxime bridging groups
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 95-96
- https://doi.org/10.1039/c39740000095
Abstract
An unusual dimeric structure with tetragonally co-ordinated copper(II) ions, bridged by oxime groups into six-membered rings, has been found for CuLCIO4·H2O, where L represents the anion of 2-(2-hydroxyethyl)imine-3-oximatobutane; the low magnetic moment per copper atom (0·25 B.M.) results from superexchange coupling through the bridge.Keywords
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