Structure and catalytic activity of CoχMg1–χAl2O4 spinel solid solutions. Part 1.—Cation distribution of Co2+ ions
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Vol. 73, 1972-1982
- https://doi.org/10.1039/f19777301972
Abstract
The cation distribution in CoAl2O4 and in several CoχMg1–χAl2O4 solid solutions with χ ranging from 0.05 to 0.5 has been studied by magnetic susceptibility, reflectance spectroscopy, lattice parameter variation and analysis of some X-ray reflections whose intensities are particularly sensitive to variation in cation positions. The results show that all specimens have the cobalt ions in a predominantly tetrahedral distribution and that there is a change towards a random cation distribution when the preparation temperature is increased from 1073 to 1473 K. The fraction of Co2+ ions in tetrahedral sites, α, is equal to 0.82 and 0.77 for the CoAl2O4 spinel prepared at 1073 and 1473 K, respectively. The X-ray results show, moreover, that α does not vary significantly with composition for χ varying from 1.0 to 0.1. For the most dilute cobalt solid solution (χ= 0.05), however, the value of α is lower; this trend is observed in both series of specimens prepared at different temperatures and may be explained in terms of anion–anion contact effects.Keywords
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