Phosphinoborane and Sulfidoborohydride as Chelating Ligands in Polyhydride Ruthenium Complexes: Agostic σ‐Borane versus Dihydroborate Coordination
- 30 March 2009
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 48 (16) , 2964-2968
- https://doi.org/10.1002/anie.200806178
Abstract
A question of coordination mode: Two new borane compounds are prepared. They act as bifunctional ligands as illustrated by their reaction with ruthenium polyhydrides which leads to the formation of two complexes (see scheme) displaying either a δ-agostic interaction of a η2-BH bond involving a trivalent boron atom or a dihydroborate ligation.Keywords
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