Allylsilane cyclisations in organic synthesis; formation of a cyclopentane via cyclisation of an epoxy-allylsilane
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 585-586
- https://doi.org/10.1039/c39840000585
Abstract
The epoxy-allylsilane (1) was prepared by two routes and cyclised stereoselectively to give the cis-cyclopentane (9) on treatment with TiCl4; equilibration of the aldehyde corresponding to (9) gave the trans-isomer in high yield.Keywords
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