σ- and π-Bonded dinitrile complexes of MnIand ReIcarbonyl halides
- 1 January 1972
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 513
- https://doi.org/10.1039/c39720000513
Abstract
The existence of both monomeric π-bonded dinitriles and dimeric σ-bonded dinitriles is postulated and its is suggested that the monomeric π-complexes are the kinetically favoured species, whereas the σ-bonded complexes are the thermodynamically favoured form.Keywords
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