Study of the Electrochemical Properties of C60Modified Carbon Paste Electrode and Its Application for Nitrobenzene Quantitation Based on Electrocatalytic Reduction
- 1 January 1997
- journal article
- research article
- Published by Taylor & Francis in Analytical Letters
- Vol. 30 (2) , 367-381
- https://doi.org/10.1080/00032719708002809
Abstract
A C60 modified carbon paste electrode(MCPE) was prepared and its electrochemical properties in tetrabutylammonium hydroxide/CH3CN/H2O solutions were studied. Two pairs of mono-electron quasi-reversible redox peaks were obtained and characterized. The experimental results revealed that this electrode had a good electrocatalytic reduction response for nitrobenzene in these conditions. The catalytic reduction current had a good linear relationship to the concentration of nitrobenzene. The linear range of nitrobenzene concentration was between 5.0×10−5∼6.0×10−3mol/L. The detection limit was 3.0×10−5mol/L.Keywords
This publication has 13 references indexed in Scilit:
- Simultaneous cyclic voltammetry and electrochemical quartz crystal microbalance studies of buckminsterfullerene (C60) film electrodeposition and tetra-n-butylammonium electrodoping in acetonitrileThe Journal of Physical Chemistry, 1992
- Electronic structure, conductivity and superconductivity of alkali metal doped (C60)Accounts of Chemical Research, 1992
- Electrochemical detection of fulleronium and highly reduced fulleride (C605-) ions in solutionJournal of the American Chemical Society, 1991
- Electrochemical reduction and oxidation of C60 filmsJournal of the American Chemical Society, 1991
- Spectroelectrochemical study of the C60 and C70 fullerenes and their mono-, di-, tri- and tetraanionsJournal of the American Chemical Society, 1991
- Ab initio theoretical predictions of the equilibrium geometries of C60, C60H60 and C60F60Chemical Physics Letters, 1991
- Two different fullerenes have the same cyclic voltammetryJournal of the American Chemical Society, 1991
- Efficient production of C60 (buckminsterfullerene), C60H36, and the solvated buckide ionThe Journal of Physical Chemistry, 1990
- Solid C60: a new form of carbonNature, 1990
- Electronic structure and bonding in icosahedral C60Chemical Physics Letters, 1986