Infrared studies of cis- and trans-bis(halogenoacetato)bis(ethylenediamine)-cobalt(III) complexes
- 15 March 1969
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 47 (6) , 1073-1075
- https://doi.org/10.1139/v69-169
Abstract
The infrared spectra have been studied for cis- and trans-isomers of complexes of the type [Co(en)2(halac)2]ClO4, where en = ethylenediamine and halac = CH3CO2−, CH2ClCO2−, CHCl2CO2−, CCl3CO2−, CHBr2CO2−, and CF3CO2−. Characteristic differences between the spectra of cis- and trans-isomers have been examined and correlated with data for similar complexes. The most consistent variations are in the 500–610 cm−1 region where Co—N stretching modes occur.Keywords
This publication has 0 references indexed in Scilit: