A theory for pressure dependence of electron paramagnetic resonance zero-field splitting of NiSiF6⋅6H2O
- 15 April 1985
- journal article
- research article
- Published by AIP Publishing in Journal of Applied Physics
- Vol. 57 (8) , 3739
- https://doi.org/10.1063/1.334953
Abstract
By using the high order perturbation formula of EPR zero‐field splitting for d8 configuration in trigonal crystal field proposed by us, and using the approximate SCF d orbit of Ni2+, an interpretation for the pressure dependence of zero‐field splitting of NiSiF6⋅6H2O, which has been a still imperfectly understood problem, is given. In addition, the state equation dependent on pressure for NiSiF6⋅6H2O is predicted.This publication has 4 references indexed in Scilit:
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- Crystal structures of the fluosilicate hexahydrates of cobalt, nickel and zincActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1973
- Temperature Dependence of Paramagnetic Resonance LinesPhysical Review B, 1964
- Paramagnetic Resonance of Nickel Fluosilicate under High Hydrostatic PressurePhysical Review B, 1957