Optical Spectra of Tripositive Curium−244 in Lanthanum Trichloride
- 1 September 1966
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 45 (5) , 1423-1427
- https://doi.org/10.1063/1.1727778
Abstract
Absorption and emission optical spectra are reported for Cm3+ in LaCl3 between 3000 and 8000 Å. These data are explained in terms of the Racah, spin—orbit, and configuration‐interaction parameters: E0=4939.29 E1=4621.47, E2=17.70, E3=399.42, ζ=2841.66, α=57.08, β=−4761.60 cm−1, respectively. Crystal‐field splitting of the ground state is observed.
Keywords
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