Sulphur dioxide as an unsupported bridging ligand: synthesis and X-ray crystallographic characterization of µ-(sulphur dioxide)-bis-(π-cyclopentadienyldicarbonyliron)
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 981-982
- https://doi.org/10.1039/c39720000981
Abstract
[π-C5H5Fe(CO)2]2SO2 has been prepared from π-C5H5Fe(CO)2Na and SO2 and its molecular stereochemistry determined from a single-crystal X-ray diffraction study; this complex represents the first known molecule in which SO2 alone bridges two transition metal atoms.Keywords
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