Thermodynamic, NMR and photochemical study on the acid–base behaviour of N,N′-dibenzylated polyamines and on their interaction with hexacyanocobaltate(III)
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 11,p. 2335-2342
- https://doi.org/10.1039/p29960002335
Abstract
The synthesis and protonation behaviour of the dibenzylated open-chain ligands 1,4-dibenzyl-1,4-diazabutane (L1), 1,7-dibenzyl-1,4,7-triazaheptane (L2), 1,10-dibenzyl-1,4,7,10-tetraazadecane (L3), 1,12-dibenzyl-1,5,8,12-tetraazadodecane (L4) and 1,13-dibenzyl-1,4,7,10,13-pentaazatridecane (L5) are presented. The protonation behaviour has been studied by means of pH-metric measurements, NMR, absorption UV–VIS and steady-state fluorescence emission spectroscopy. The influence of the aromatic ring on the acid–base behaviour of these ligands is discussed. The association constants of these ligands with [Co(CN)6]3– have been calculated by steady-state fluorescence emission. The reduction in the quantum yield for the photoaquation reaction of [Co(CN)6]3– in the presence of L5 suggests that three out of the six cyanide groups of the anion are involved in the formation of the hydrogen-bond network of the supramolecular adduct.Keywords
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