Synthesis of the dimetal compounds [FeW{μ-PPh2 · CH · CH2 C(C6H4Me-4)}(CO)5(η5-C5Me5)] and [FeMo{μ-PPh2 · CH · CH2 · C(C6H4Me-4)}(CO)5(η5-C5H5)]; molecular structure of the iron-tungsten compound
- 31 December 1987
- journal article
- Published by Elsevier in Polyhedron
- Vol. 6 (12) , 2067-2071
- https://doi.org/10.1016/s0277-5387(00)84264-3
Abstract
No abstract availableThis publication has 9 references indexed in Scilit:
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- Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 56. Synthesis of iron–molybdenum compounds; crystal structures of [FeMo(µ-CR)(CO)6(η-C5H5)] and [FeMo2(µ3-RC2R)(CO)6(η-C5H5)2](R = C6H4Me-4)J. Chem. Soc., Dalton Trans., 1987
- Chemistry of di- and tri-metal complexes with bridging carbene or carbyne ligands. Part 44. Formation of unsaturated dimetal compounds with elimination of alkylidyne groups; X-ray crystal structures of [FeW(µ-PPh2)(CO)5{HB(pz)3}][HB(pz)3= tris(pyrazol-1-yl)borate] and [RhW(µ-CO)2(CO)(PPh3)2(η-C5H5)]J. Chem. Soc., Dalton Trans., 1986
- Chemistry of di- and tri-metal complexes with bridging carbene or carbyne ligands. Part 43. Carbon–tungsten triple bonds as formal four-electron donors; synthesis and reactions of the compounds [FeW(µ-CC6H4Me-4)(CO)5L]{L = HB(pz)3[tris(pyrazol-1-yl)borate] or η-C5H5} and X-ray crystal structures of [FeW(µ-CC6H4Me-4)(CO)5{HB(pz)3}] and [FeW(µ-CC6H4Me-4)(CO)(µ-Me2PCH2PMe2)(CO)2{HB(pz)3}]J. Chem. Soc., Dalton Trans., 1986
- Chemistry of di- and tri-metal complexes with bridging carbene or carbyne ligands. Part 23. Alkyne insertion into heteronuclear dimetal compounds with bridging tolylmethylidyne ligands; crystal structures of [FeW{µ-C(C6H4Me-4)C(Me)C(Me)}(CO)5(η-C5H5)] and [Fe2W(µ3-CC6H4Me-4)(µ-Me3SiC2SiMe3)(µ-CO)(CO)6(η-C5H5)]J. Chem. Soc., Dalton Trans., 1984