The nature of bonding in silver–olefin complexes: an electron spin resonance study
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 11,p. 641b-642
- https://doi.org/10.1039/c2970000641b
Abstract
Paramagnetic species have been detected in γ-irradiated silver perchlorate–cycloalkene complexes at room temperature and identified as Ag+ cycloalkenyl radical, with spin density on Ag ranging from 4·6% to 1·5% and in a decreasing order with increasing size of the alkene rings.Keywords
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