Infrared Spectrum of Bromine Pentafluoride
- 1 July 1962
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 37 (1) , 165-167
- https://doi.org/10.1063/1.1732943
Abstract
The infrared spectrum of bromine pentafluoride has been observed in the region 4000–215 cm—1 with a resolution of 0.5–1.0 cm—1. All infrared‐active fundamentals have been observed; these occur at 684, 584, and 370 cm—1 (A1) and 644, 415, and 245 cm—1 (E). The spectrum confirms the C4v (square pyramidal) structure. Corrections are given for the previously reported thermodynamic functions.Keywords
This publication has 15 references indexed in Scilit:
- TETRAFLUOROHALATES OF CESIUM, RUBIDIUM AND POTASSIUM1Journal of the American Chemical Society, 1961
- BOND LENGTHS AND BOND ANGLES IN OCTAHEDRAL, TRIGONAL- BIPYRAMIDAL, AND RELATED MOLECULES OF THE NON-TRANSITION ELEMENTSCanadian Journal of Chemistry, 1961
- Infrared Studies of the Bromine Fluorides1Journal of the American Chemical Society, 1959
- Bromine Pentafluoride. The Electric Dipole Moment in the Vapor State and the Dielectric Constant of the Liquid1Journal of the American Chemical Society, 1956
- Reviews of booksTransactions of the Faraday Society, 1955
- Directed valency in elements of the first and second short periodsTransactions of the Faraday Society, 1954
- The Raman Spectrum, Structure, Force Constants, and Thermodynamic Properties of Bromine PentafluorideThe Journal of Chemical Physics, 1952
- Nuclear Magnetic Shielding in Fluorine and Hydrogen CompoundsThe Journal of Chemical Physics, 1951
- The Vibrational Spectra and Structures of Iodine Pentafluoride and Heptafluoride1,2Journal of the American Chemical Society, 1950
- The Envelopes of Infrared Absorption BandsPhysical Review B, 1933