Trimethylsilylation of Ag10Si4O13: cyclisation of the linear chain anion Si4O13 10?
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 576-577
- https://doi.org/10.1039/c39800000576
Abstract
Trimethylsilylation of Ag10Si4O13 by a modified ‘direct method’ yielded the trimethylsilyl (TMS) derivative of the linear chain ion Si4O13 10– as the major product; this ion readily undergoes cyclisation in acidic aqueous media to yield the cyclic tetramer Si4O12 8– and the presence of linear and branched chain isomers of the TMS derivative of Si4O13 10– was confirmed in the tri-methylsilylation of lead fluorosilicate glass.Keywords
This publication has 0 references indexed in Scilit: