Molecular recognition and the design of solid state structures: protonation-induced conformational change and self-assembly of 2,6-diamidopyridinium phosphates
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1283-1285
- https://doi.org/10.1039/c39910001283
Abstract
Protonation of 2,6-diamidopyridine with diaryl phosphates leads to a conformational change in the pyridine from inwardly to outwardly directed amide-NH groups and a resultant self-assembly of the anion and cation into an alternating cocrystal with a novel hydrogen bonding motif.Keywords
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