Studies of the Gaussian model
- 10 August 1992
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 76 (5) , 1093-1101
- https://doi.org/10.1080/00268979200101901
Abstract
A two-component version of the continuum Gaussian model shows a separation into two fluid phases at high densities. We analyse its behaviour by calculating the cluster integrals and virial coefficients up to 13th order for systems of dimensionality, d, from 2 to 10. We show that there is strong evidence that for d ⩾ 4 the system has a classical critical point but that its behaviour is quite different for d = 2 and 3. The best value of the critical exponent that governs the divergence of the susceptibility, γρ, is 1·55 for d = 3, but a virial expansion to at least 20th order would be needed to give an accurate estimate and our result does not rule out the value of 1·39 that would be expected from a member of the Ising universality class.Keywords
This publication has 6 references indexed in Scilit:
- Studies of the gaussian modelMolecular Physics, 1991
- The Gaussian model of a fluid in dimensions D=0, -2: an exact solutionJournal of Physics A: General Physics, 1986
- Penetrable Sphere Models of Liquid‐Vapor EquilibriumAdvances in Chemical Physics, 1980
- Plait Points in Two- and Three-Component Liquid MixturesThe Journal of Chemical Physics, 1967
- Critical Solution Behavior in a Binary Mixture of Gaussian MoleculesThe Journal of Chemical Physics, 1964
- The Enumeration of Point Labelled Chromatic Graphs and TreesCanadian Journal of Mathematics, 1960