Crystal and molecular structures of bis(1,3-di-tert-butylcyclopentadienyl)cerium chloride and borohydride. First example of the bridging tetradentate BH4-group with two μ3-hydrogens: μ : η4-[(μ3-H)2B(μ2-H)2]
- 1 April 1991
- journal article
- Published by Elsevier in Journal of Organometallic Chemistry
- Vol. 406 (3) , 343-352
- https://doi.org/10.1016/0022-328x(91)83122-k
Abstract
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This publication has 10 references indexed in Scilit:
- The crystal and molecular structure of the 20-electron alumohydride complex of bis(t-butylcyclopentadienyl)samarium {[(η5-C5H4But)2Sm(μ3-H)][(μ2-H)2AlH·OC4H8]}2Journal of Organometallic Chemistry, 1990
- Tetrahydroborate complexes of uranium: Preparation and crystal structure of mixed-valent [Na(THF)6] [(C5Me5)U(BH4)3]2Inorganica Chimica Acta, 1989
- Bimetallic ruthenium hydride borohydride complex with unusually short ruthenium-boron distances. X-ray crystal structure of (.mu.,.eta.2-tetrahydroborato)dihydridobis[tris(diphenylphosphinomethyl)ethane]diruthenium(1+) tetraphenylborateInorganic Chemistry, 1986
- Bridging of thorium by hydrogen atoms of methyltrihydroborate groups. Crystal structures of bis[tetrakis(methyltrihydroborato)thorium(IV)] etherate and bis[tetrakis(methyltrihydroborato)thorium(IV) tetrahydrofuranate]Inorganic Chemistry, 1985
- (Pentamethylcyclopentadienyl)iridium polyhydride complexes: synthesis of intermediates in the mechanism of formation of (pentamethylcyclopentadienyl)iridium tetrahydride and the preparation of several iridium(V) compoundsJournal of the American Chemical Society, 1985
- Bonding in transition-metal tetrahydroborates: a multinuclear magnetic resonance study of (C5H5)2Sc(BH4) and Sc(BH4)3 and some comments on the isolobality of BH4-, halide, and .eta.5-C5H5- groupsInorganic Chemistry, 1984
- Organolanthanide hydride chemistry. 3. Reactivity of low-valent samarium with unsaturated hydrocarbons leading to a structurally characterized samarium hydride complexJournal of the American Chemical Society, 1983
- Covalent transition metal, lanthanide, and actinide tetrahydroborate complexesChemical Reviews, 1977
- Structure and chemistry of bis(cyclopentadienyl)-MLn complexesJournal of the American Chemical Society, 1976
- Preparation of anhydrous lanthanide halides, especially iodidesJournal of Inorganic and Nuclear Chemistry, 1962