A Facile Method for the Preparation of Functionalized 2-Halo-1-olefins
- 1 February 1993
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 23 (4) , 525-529
- https://doi.org/10.1080/00397919308009808
Abstract
Highly functionalized 2-halo-1-olefins were prepared by the reaction of functionalized organozinc halides with 2,3-dihalopropene catalyzed by Cu(I) salts. Yields are high to excellent.Keywords
This publication has 9 references indexed in Scilit:
- A facile method for the preparation of functionalized 2,3-disubstituted-1,3-butadienesTetrahedron Letters, 1991
- The direct formation of functionalized alkyl(aryl)zinc halides by oxidative addition of highly reactive zinc with organic halides and their reactions with acid chlorides, .alpha.,.beta.-unsaturated ketones, and allylic, aryl, and vinyl halidesThe Journal of Organic Chemistry, 1991
- Synthesis and reactivity toward acyl chlorides and enones of the new highly functionalized copper reagents RCu(CN)ZnIThe Journal of Organic Chemistry, 1988
- Hydrolytic selenoxide elimination reaction for the preparation of 2-chloro-1-olefinsTetrahedron Letters, 1987
- 3-Halovinylglycines. Efficient irreversible inhibitors of Escherichia coli alanine racemaseJournal of the American Chemical Society, 1987
- A New Route to 2-Bromo-1-alkenes by Hydrobromination of 1-Alkynes with Tetraethylammonium Hydrogen DibromideSynthesis, 1980
- The synthesis of vinyl bromides and allyl bromides from monosubstituted alkenes.Tetrahedron Letters, 1977
- Ionic additions to unsaturated systems. Part 2. Triethylammonium hydrogendichloride as reagent in the addition of hydrogen chloride to alkynesJournal of the Chemical Society, Perkin Transactions 1, 1977
- Chloroolefin annelationAccounts of Chemical Research, 1972