Dynamic stereochemistry: mechanistic controversy in the silver oxide–bromine induced cyclizations of alcohols
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 451-452
- https://doi.org/10.1039/c39730000451
Abstract
The abstraction of a diastereotopic hydrogen (1,4) in the silver oxide–bromine catalysed formation of tetrahydrofurans from three acyclic secondary alcohols has been shown to be stereoanalogous to the hydrogen abstraction in lead tetra-acetate generated alkoxy-radicals in the same molecules.Keywords
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