Preparation and crystal structure of the addition compound MeLi·U[OCH(CMe3)2]4, a compound with a uranium to carbon σ-bond
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1846-1847
- https://doi.org/10.1039/c39870001846
Abstract
Reaction of MeLi and U[OCH(CMe3)2]4 gives the addition compound, LiU(Me)[OCH(CMe3)2]4 which in the solid state has a geometry based upon square pyramidal uranium with the apical site occupied by a methyl group and the four basal sites being occupied by oxygen atoms of the alkoxide ligand, two of which form bridges to the lithium atom.Keywords
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